BBC to show Celtic v Hearts cup tie live
The match at Celtic Park will kick off at 19:15 BST on Wednesday, 24 September and it was also be available to UK users via the BBC Sport website.
Hearts were 1-0 winners in the east end of Glasgow in 2009 when the teams last faced each other in the competition.
But Celtic have won the last eight meetings, including a 7-0 victory in last season's Scottish Cup.
Hearts lost in the 2013 final and have won the trophy on four occasions, the last success coming in 1962, while Celtic have lifted the League Cup 14 times.